Reactions of H3Al NMe3 with E(SiMe3)3 (E = P, As). Structural Characterization of the Trimer H2AlP(SiMe3)23 and Base-Stabilized Adduct H2AlAs(SiMe3)2 NMe3, and Their Thermal Decomposition Toward Nanocrystalline AlP and AlAs, Respectively
by J. F. Janik
This paper details the reactions of H3Al·NMe3 with E(SiMe3)3 (E = P, As), including structural analysis of the trimer H2AlP(SiMe3)2·3 and adduct H2AlAs(SiMe3)2·NMe3. It further explores their thermal decomposition to form nanocrystalline AlP and AlAs, offering insights into synthetic pathways for these materials.
About This Book
The study investigates the chemical reactions between H3Al·NMe3 and E(SiMe3)3 where E represents phosphorus or arsenic.
It provides structural characterization of the trimer H2AlP(SiMe3)2·3 and the base-stabilized adduct H2AlAs(SiMe3)2·NMe3.
Additionally, the research examines their thermal decomposition processes, resulting in nanocrystalline aluminum phosphide (AlP) and aluminum arsenide (AlAs), respectively.
Authored by J. F. Janik, this work contributes to understanding organometallic synthesis and material properties in inorganic chemistry.
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